4-methyl cyclohexane methanol msds pdf

In vitro cytotoxicity assessment of a west virginia. On january 9, 2014, there was an accidental release into the elk river in west virginia of an estimated 10,000 gallons of a mixture of these chemicals1. Meoh methanol cas 67561 common usage mmchc methyl 4 methylcyclohexane1carboxylate cas 51181409 this study mmchm 4 methoxymethyl cyclohexane methanol cas 98955272 this study msds material safety data sheet nlm us national library of medicine noael noobservedadverseeffect level noec no observed effect concentration. Cyclohexane, 1methyl41methylethyl, trans cas 167882. Health effects for chemicals in 2014 west virginia. Recommendation for 2,4dimethyl3cyclohexene1methanol usage levels up to. Find more compounds similar to cyclohexane, 1methyl41methylethyl, cis. Finish cleaning the spill by rinsing any contaminated surfaces with copious amounts of water.

A heated purgeandtrap gas chromatographymass spectrometry method was used to determine the cis and transisomers of 4 methylcyclohexylmethanol 4mchm, the reported major component of the crude mchmdowanol pph glycol ether material spilled into the elk river upriver from charleston, west virginia, on january 9, 2014. Consult federal, state, andor local authorities for assistance on disposal. Identification methylcyclohexane is a colorless liquid with a faint, benzenelike odor. Hello rchemistry, i live in the charleston, wv area, and currently, 8 counties are in a state or emergency due to a leak of 4 methylcyclohexane methanol, a chemical used to clean mining equipment. Material safety data sheet gasoline, all grades msds no. The 2014 west virginia chemical spill has raised public attention to 4 methylcyclohexyl methanol 4 mchm, one cyclohexane derivative, which is widely used in coal processing but largely ignored. Use this link for bookmarking this species for future reference.

In the yeast library, 4mchm mainly induced chemical stress related to transmembrane. Toxicity assessment of 4methyl1cyclohexanemethanol and. We can serve well quality product and the way of our traffic is safty and efficently. Methylcyclohexane is a flammable liquid and a dangerous fire hazard. When it is reacted with ki, im told that i should get 4 methyl cyclohexene. Classified as a saturated higher alicyclic primary alcohol. These metabolites may cause metabolic acidosis, visual disturbances and blindness. Information provided on 1cyclohexene1methanol, 4 1methylethenyl, acetate 15111963 is for reference only and is subject to change. Jan 10, 2014 little is known about the safety implications for 4 methylcyclohexane methanol, according to the states poison control director dr.

Predicted data is generated using the us environmental protection agencys episuite. Cyclohexane 121 cyclohexane cis1,2dicarboxylic acid 122 cis1,2cyclohexanediol 123 trans1,2cyclohexanediol 124 cyclohexanol 125 cyclohexanone 126 cyclohexanone semicarbazone 127 cyclohexyl bromide 53 cyclohexene 128. Toxicity assessment of 4methyl1cyclohexanemethanol and its. Any monosubstituted ciclohexane has an axis of simmetry thus it is superimposable to its mirror image. A considerable number of people were reported to exhibit symptoms of chemical exposure and an estimated 300,000 residents were advised not to use or drink tap water. Eastman chemical companys msds for crude unpurified mchm. Gasoline methanol blend the blending of gasoline petrol with approximately 15 volume percent methanol m15 along with cosolvents and corrosion inhibitors. Cyclohexane 121 cyclohexanecis1,2dicarboxylic acid 122 cis1,2cyclohexanediol 123 trans1,2cyclohexanediol 124 cyclohexanol 125 cyclohexanone 126 cyclohexanone semicarbazone 127 cyclohexyl bromide 53 cyclohexene 128. The general approach towards carrying out an organic reaction. For air samples, method 5041 provides methodology for desorbing vocs from trapping media methods 0010, 0030, and 0031. There is no warranty of accuracy or completeness of any information contained herein. Request pdf toxicity assessment of 4methyl1cyclohexanemethanol and its metabolites in response to a recent chemical spill in west virginia, usa the largescale chemical spill on january 9. Elizabeth scharman because it hasnt been adequately studied. Find more compounds similar to cyclohexane, 1methyl4 1methylethyl, trans.

Show this material safety data sheet to the doctor in attendance. Health effects for chemicals in 2014 west virginia chemical. It is also used in the preparation of n,ndiethyldithiocarbamate functionalized 1,4polyisoprenes. However, the problem asks us to consider that small. Cyclohexanemethanol, 4methyl substance information echa. V safety data sheet for 4methyl1cyclohexanemethanol cis and trans.

Meoh methanol cas 67561 common usage mmchc methyl 4methylcyclohexane1carboxylate cas 51181409 this study mmchm 4methoxymethyl cyclohexane methanol cas 98955272 this study msds material safety data sheet nlm us national library of medicine noael noobservedadverseeffect level noec no observed effect concentration. Similiar molecules click here to search for similiar molecules. The 2014 west virginia chemical spill has raised public attention to 4methylcyclohexylmethanol 4mchm, one cyclohexane derivative, which is widely used in coal processing but largely ignored. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is. It is used as a solvent and to manufacture organic chemicals. The source is also providing more information like the publication year, authors and more. Take the time to validate and double check the source of the data. Remember that the definition of chiral molecule is one which isnt superimposable to its mirror image a chiral centre isnt strictly neces. Recommendation for 2,4dimethyl3cyclohexene1methanol flavor usage levels up to. Background 4 methyl cyclohexane methanol mchm and propylene glycol phenyl ether pph are chemicals used in the coal cleaning process. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. It is also used in the preparation of n,ndiethyldithiocarbamate functionalized 1, 4 polyisoprenes.

Read label before use keep container tightly closed avoid release to the environment do not eat, drink or smoke when using this product. Recommendation for 2, 4 dimethyl3cyclohexene1 methanol usage levels up to. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Thousands of gallons of industrial chemicals, crude 4methylcyclohexanemethanol mchm and propylene glycol phenyl ether pph, leaked from industrial tanks into the elk river in charleston, west virginia, usa, on january 9, 2014.

I dont understand how both bromines can be eliminated without losing any hydrogens, and the conditions of the reaction dont seem to be quite right for either e1 or e2 elimination reactions. Find manufacturers and suppliers for 4methylcyclohexanecarboxylic acid, 64830. Synthesis of cyclohexene the dehydration of cyclohexanol. The transisomer eluted first and method detection limits were 0. Cyclohexane, 1methyl41methylethyl, cis cas 6069983. I dont understand how both bromines can be eliminated without losing any hydrogens, and the conditions of the reaction dont seem to. Safety data sheet according to federal register vol. Us eu fda jecfa fema flavis scholar patent information. Extremely flammable eye and mucous membrane irritant effects central nervous system harmful or fatal if swallowed aspiration hazard high fire hazard. Methanol is metabolized to formaldehyde and formic acid. Recommendation for 2, 4 dimethyl3cyclohexene1 methanol flavor usage levels up to. Safety data sheet according to 29cfr19101200 and ghs rev.

Leave a comment on 4 methylcyclohexane methanol msds pdf 4methylcyclohexanemethanol mchm, systematic name 4 methylcyclohexylmethanol is an eastman chemical companys msds for crude unpurified mchm, as supplied by npr, reports an oral ld of mg kg and a dermal ld product name. Cyclohexanemethanol, 4methyl regulatory process names 1 other identifiers 1. Hello rchemistry, i live in the charleston, wv area, and currently, 8 counties are in a state or emergency due to a leak of 4methylcyclohexane methanol, a chemical used to clean mining equipment. Safety evaluation of certain food additives and contaminants pdf. A considerable number of people were reported to exhibit symptoms of chemical exposure and an estimated 300,000 residents were advised not to use. Methylcyclohexane may affect the liver and kidneys. Sw846 update vi 8260d 6 revision 4 june 2018 solid, oil and tissue samples. When it is reacted with ki, im told that i should get 4methylcyclohexene.

Reason for citation methylcyclohexane is on the hazardous substance list. Little is known about the safety implications for 4methylcyclohexane methanol, according to the states poison control director dr. Chemeo is only indexing the data, follow the source links to retrieve the latest data. Both cis and trans isomers exist, depending on the relative positions of the methyl ch 3 and hydroxymethyl ch 2 oh groups on the cyclohexane ring. Mar 29, 2017 thousands of gallons of industrial chemicals, crude 4 methylcyclohexanemethanol mchm and propylene glycol phenyl ether pph, leaked from industrial tanks into the elk river in charleston, west virginia, usa, on january 9, 2014. Material safety data sheet gasoline, all grades msds. This sample safety data sheet ssds provides information for m15. Cyclohexanecarboxylic acid an overview sciencedirect. In vitro cytotoxicity assessment of a west virginia chemical. Solid phase microextraction spme method for 4methyl1.